Abstract: The human visual system and most digital cameras sample the continuous spectral power distribution through three classes of receptors. This implies that two distinct spectral reflectances can result in identical tristimulus values under one illuminant and differ under another – the problem of metamer mismatching. It is still debated how frequent this issue arises in the real world, using naturally occurring reflectance functions and common illuminants.
We gathered more than ten thousand spectral reflectance samples from various sources, covering a wide range of environments (e.g., flowers, plants, Munsell chips) and evaluated their responses under a number of natural and artificial source of lights. For each pair of reflectance functions, we estimated the perceived difference using the CIE-defined distance ΔE2000 metric in Lab color space.
The degree of metamer mismatching depended on the lower threshold value l when two samples would be considered to lead to equal sensor excitations (ΔE < l), and on the higher threshold value h when they would be considered different. For example, for l=h=1, we found that 43.129 comparisons out of a total of 6×107 pairs would be considered metameric (1 in 104). For l=1 and h=5, this number reduced to 705 metameric pairs (2 in 106). Extreme metamers, for instance l=1 and h=10, were rare (22 pairs or 6 in 108), as were instances where the two members of a metameric pair would be assigned to different color categories. Not unexpectedly, we observed variations among different reflectance databases and illuminant spectra with more frequency under artificial illuminants than natural ones.
Overall, our numbers are not very different from those obtained earlier (Foster et al, JOSA A, 2006). However, our results also show that the degree of metamerism is typically not very strong and that category switches hardly ever occur.

Abstract: The segmentation of visible electromagnetic radiation into chromatic categories by the human visual system has been extensively studied from a perceptual point of view, resulting in several colour appearance models. However, there is currently a void when it comes to relate these results to the physiological mechanisms that are known to shape the pre-cortical and cortical visual pathway. This work intends to begin to fill this void by proposing a new physiologically plausible model of colour categorization based on Neural Isoresponsive Colour Ellipsoids (NICE) in the cone-contrast space defined by the main directions of the visual signals entering the visual cortex. The model was adjusted to fit psychophysical measures that concentrate on the categorical boundaries and are consistent with the ellipsoidal isoresponse surfaces of visual cortical neurons. By revealing the shape of such categorical colour regions, our measures allow for a more precise and parsimonious description, connecting well-known early visual processing mechanisms to the less understood phenomenon of colour categorization. To test the feasibility of our method we applied it to exemplary images and a popular ground-truth chart obtaining labelling results that are better than those of current state-of-the-art algorithms.