Abstract: Automatic waste recycling has become a very important societal challenge nowadays, raising people’s awareness for a cleaner environment and a more sustainable lifestyle. With the transition to Smart Cities, and thanks to advanced ICT solutions, this problem has received a new impulse. The waste recycling focus has shifted from general waste treating facilities to an individual responsibility, where each person should become aware of selective waste separation. The surge of the mobile devices, accompanied by a significant increase in computation power, has potentiated and facilitated this individual role. An automated image-based waste classification mechanism can help with a more efficient recycling and a reduction of contamination from residuals. Despite the good results achieved with the deep learning methodologies for this task, the Achille’s heel is that they require large neural networks which need significant computational resources for training and therefore are not suitable for mobile devices. To circumvent this apparently intractable problem, we will rely on knowledge distillation in order to transfer the network’s knowledge from a larger network (called ‘teacher’) to a smaller, more compact one, (referred as ‘student’) and thus making it possible the task of image classification on a device with limited resources. For evaluation, we considered as ‘teachers’ large architectures such as InceptionResNet or DenseNet and as ‘students’, several configurations of the MobileNets. We used the publicly available TrashNet dataset to demonstrate that the distillation process does not significantly affect system’s performance (e.g. classification accuracy) of the student network.